A radiation, explosives, and special materials, detection and identification system includes a housing supporting one or more gamma sensors and one or more solid-state neutron sensors proximate to container contents under examination. The system collects radiation data from the sensors and compares the collected data to one or more stored spectral images representing one or more isotopes to identify one or more isotopes present. The identified one or more isotopes present are corresponded to possible materials or goods that they represent. The possible materials or goods are compared with the manifest relating to the container to confirm the identity of materials or goods contained in the container or to detect and/or identify unauthorized materials or goods in the container. A battery powered sensor arrangement is also disclosed.